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Study of the Behavior of Electrolytes (Ionophores) Limiting Molar Conductivities of Electrolytes and Individual Ions; Ionic Association Constants; Formation Constants of Triple Ions As mentioned in Section 7.1, if we determine the molar conductivity of an electrolyte as a function of its concentration and analyze the data, we can get the value of limiting molar conductivity KI and quantitative information about ion association and triple-ion formation. If we determine the limiting molar conductivity of an ion kI by one of the methods described in Section 7.2, we can determine i the radius of the solvated ion and calculate the solvation number. It is also possible to judge the applicability of Walden s rule to the ion under study. These are the most basic applications of conductimetry in non-aqueous systems and many studies have been carried out on these problems [1 7]. Various theories have been proposed for analyzing the data of the K c relation, by taking into account both the long-range and the short-range interactions between ions (Section 7.1.1). All of them give approximately the same KI values. Moreover, they give approximately the same values of ion association constant (KA), as far as the KA values are large enough. However, it is necessary to use a single theory in order to compare the resulting data of K and KA for a series of electrolytes. For practical information on how to analyze conductivity data, the report by Kay et al. [33], dealing with the conductivity of alkali metal salts in acetonitrile, is useful. Some reports compare the results of various theories [34]. For methods of studying triple-ion formation, some reviews and original papers are available [18, 35]. code 128 crystal reports free How to Create a Code 128 Barcode in Crystal Reports using the ...
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