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Chance Trigger FIGURE A-7: Not all bends need to be kept connected to produce an interesting bent response. As you explore your circuits you ll eventually find two points that when briefly connected will initiate an on-going disruption of circuit activity (as seen in the SA-2 Aleatron in the projects chapters). The brief connection needed to create this response must be of the correct power to best initiate the unusual audio activity. Too much juice flowing through the connection equals a crash; too little juice, and nothing happens at all. Notice the potentiometer in the drawing. This pot regulates the amount of current flowing through the bend. Once it has been set correctly, a quick tap of the partner push button switch (a normally open mini switch) will apply the needed mini-zap to set the bent circuit response off.

These were the last long-term Treasury financings until 1971 An entirely new and revolutionary phase of bond market history began in 1965 The Great Society program was under way, and business was assured that never again would even the smallest recession be permitted And many believed just this There seemed to be no more risk Besides this already inflationary setting, the war in Vietnam was escalating The new era began quietly enough in 1965 with a continued rise in short-term interest rates, which carried three-month Treasury bills from 381% up to 447% The Federal Reserve was exerting mild pressure, and the discount rate had been raised from 350 to 4% in late 1964 Nevertheless, bond yields remained almost unchanged until late in the year Then suddenly the market collapsed, led by a sharp decline in the bellwether, the recently issued Treasury 41 4s of 1987 1992.

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There are interlamellar or intercrystalline brils (also termed tie molecules) between the lamellar brils within a spherulite and between brils of different spherulites Some polymer molecules simultaneously participate in the growth of two or more adjacent lamellae and provide molecular links that reinforce the crystalline structure The chain axes of tie molecules lie parallel to the long axes of the link each link between lamellae is an extended-chain type of single crystal The tie molecules are the main component of the modern picture of polymer crystallinity, which is a carryover from the fringed-micelle theory The amorphous content of a semicrystalline, melt-crystallized polymer sample consists of the defects in the chain-folding structure, tie molecules, and the material that is either, because of entanglements, not included in the growing lamellar bril or is rejected from it owing to its unacceptable nature; lowmolecular-weight chains and nonregular polymer chain segments, for example, are excluded.

Some natural polymers such as cotton, slik, and cellulose have the extended-chain morphology, but their morphologies are determined by enzymatically controlled synthesis and crystallization processes Extended-chain morphology is obtained in some synthetic.

polymers under certain circumstances. These include crystallization from the melt (or annealing for long time periods) under pressure or other applied stress and crystallization of polymers from the liquid crystalline state. The former has been observed with several polymers, including polyethylene and polytetra uoroethylene. The latter is observed with polymers containing stiff or rigid-rod chains, such as poly(p-phenyleneterephthalamide) (Sec. 2-8f). Extended-chain morphology is also obtained in certain polymerizations involving conversion of crystalline monomer to crystalline polymer, for example, polymerization of diacetylenes (Sec. 3-16c). A variety of techniques have been used to determine the extent of crystallinity in a polymer, including X-ray diffraction, density, IR, NMR, and heat of fusion [Sperling, 2001; Wunderlich, 1973]. X-ray diffraction is the most direct method but requires the somewhat dif cult separation of the crystalline and amorphous scattering envelops. The other methods are indirect methods but are easier to use since one need not be an expert in the eld as with X-ray diffraction. Heat of fusion is probably the most often used method since reliable thermal analysis instruments are commercially available and easy to use [Bershtein and Egorov, 1994; Wendlandt, 1986]. The dif culty in using thermal analysis (differential scanning calorimetry and differential thermal analysis) or any of the indirect methods is the uncertainty in the values of the quantity measured (e.g., the heat of fusion per gram of sample or density) for 0 and 100% crystalline samples since such samples seldom exist. The best technique is to calibrate the method with samples whose crystallinites have been determined by X-ray diffraction. 1-5b Determinants of Polymer Crystallinity

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